Dibromidobis[1-(2,4,6-trimethyl­phen­yl)-1,4,5,6-tetra­hydro­pyrimidine-κN 3]palladium(II)

نویسندگان

  • Pu Mao
  • Xiujun Liu
  • Liangru Yang
  • Jinwei Yuan
  • Maoping Song
چکیده

In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra-hydro-pyrimidine group of the N-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C-N-Pd-Br torsion angle of 81.8 (4)°; this is different from the angle of 43.47 (14)°, reported in a closely related structure, dichloridobis(1-methyl-1,4,5,6-tetra-hydro-pyrimidine)-palladium(II).

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2010